Chaos and dynamical localization in Rydberg atoms

The pioneering experiment of Bayfield and Koch performed in 1974 [1] attracted a great  interest in the ionization of highly excited hydrogen and Rydberg atoms in a microwave field. The main reason of this interest is due to the fact that such ionization requires the absorption of a large number of  photons (about 20-70) and can be explained only as a result of the appearence of dynamical chaos and diffusive energy excitation in the corresponding classical system.
Quantum interference effects can suppress this diffusion leading to quantum localization of chaos [2].


Chaotic enhancement in the microwave ionization of Rydberg atoms

We have studied analytically and numerically the microwave ionization of internally chaotic Rydberg atoms [3]. The internal chaos is induced by magnetic or static electric fields. This leads to a chaotic enhancement of microwave excitation. The dynamical localization theory  gives a detailed description of the excitation process even in a regime where up to few thousands photons are required to ionize one atom. We have also discussed possible laboratory experiments.

Magnetic-field induced enhancement of the localization length.


The same chaotic enhancement mechanism has been found in:

(i) the weak interaction enhancement due to a complex structure of ergodic eigenfunctions in nuclei [4].

(ii) the
enhancement of the localization length for two interacting particles in a random potential [5].


Quantum Poincare recurrences for hydrogen atoms in a microwave field


We have studied the time dependence of the ionization probability of Rydberg atoms driven by a microwave field, both in classical and in quantum mechanics [6]. The quantum survival probability follows the classical one up to the Heisenberg time and then decays algebraically as P(t) proportional to 1/t. This decay law derives from the exponentially long times required to escape from some region of the phase space, due to tunneling and localization effects. This result implies that correlations in practice do not decay up to very long times and has analogies with the 1/f noise found, for instance, in the resistance fluctuations of different solid state devices. This phenomenon indicates a broad distribution of time scales in the system: In the case of quantum Poincare recurrences this property stems from the exponentially low escape rate from some regions of the phase space.



1/t decay of the quantum survival probability for realistic experimental conditions






Classical density plot (left) and Husimi function (right) in action-angle variables, for 50<t<60 (top) and 2000<t<10000 (right). At long times the quantum diffusion is slowed down due to localization effects

We have also shown that quantum fractal fluctuations of the survival probability can be observed in the deep quantum regime of strong localization, due to the slow, purely quantum algebraic decay in time [P(t) proportional to 1/t] produced by dynamical localization [7].


References

[1] J.E. Bayfield and P.M. Koch Phys. Rev. Lett. 33, 258 (1974); P.M. Koch and K.A.H.van Leeuwen, Phys. Rep. 255, 289 (1995).
[2] G. Casati, I. Guarneri, and D.L. Shepelyansky, IEEE Journal of Quantum Electronics 24, 1420 (1988).
[3] G. Benenti, G. Casati and D.L. Shepelyansky, Chaotic enhancement in microwave ionization of Rydberg atoms, Eur. Phys. J. D 5, 311 (1999).
[4] O.P.Sushkov and V.V.Flambaum, Usp. Fiz. Nauk 136, 3 (1982) [ Sov. Phys. Usp.  25, 1 (1982)].
[5] D.L.Shepelyansky, Phys. Rev. Lett. 73, 2607 (1994).
[6] G. Benenti, G. Casati, G. Maspero and D.L. Shepelyansky, Quantum Poincare recurrences for a hydrogen atom in amicrowave field, Phys. Rev. Lett. 84, 4088 (2000).
[7] G. Benenti, G. Casati, I. Guarneri and M. Terraneo, Quantum fractal fluctuations, Phys. Rev. Lett. 87, 014101 (2001).